Academic Positions

  • Associate professor2013

    Department of Chemistry

  • Associate professor2015

    Department of Chemistry

Educations

  • 1970Bachelor of Science

    chemistry

    Ferdowsi University of Mashhad

  • 1970Master of Science

    chemistry

    Sharif University of Technology

  • 1970Ph.D

    chemistry

    پوترا

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Evaluation of Acidity Constants of Anthraquinone Derivatives in Methanol/Water Mixtures Using Real Quantum Descriptors

,Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2012 , Pages: 1-7, ISSN: Journal Paper

Abstract

Application of Artificial Neural Network for Evaluation of pKa Values and exploring the Solvation Mechanism of Phenol Derivatives

,Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2013 , Pages: 32-40, ISSN: Journal Paper

Abstract

Artificial neural network modeling studies to predict the yield of enzymatic synthesis of betulinic acid ester

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2010 , Pages: -, ISSN: Journal Paper

Abstract

Lipase-catalyzed esterification of betulinic acid using phthalic anhydride in organic solvent media: Study of reaction parameters

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2010 , Pages: 337-342, ISSN: Journal Paper

Abstract

Spectroscopic data of 3-O-acetyl-betulinic acid: An antitumor reagent

Mansour Ghaffari Moghaddam,Mahiran Basri
ثبت نشده , ثبت نشده , Year : 2010 , Pages: 3186-3192, ISSN: Journal Paper

Abstract

Anticancer activity of 3-O-acylated betulinic acid derivatives obtained by enzymatic synthesis

Mansour Ghaffari Moghaddam,Faujan Bin H Ahmad
ثبت نشده , ثبت نشده , Year : 2010 , Pages: 1025-1029, ISSN: Journal Paper

Abstract

Enzymatic synthesis of betulinic acid ester as an anticancer agent: Optimization study

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2010 , Pages: 192-200, ISSN: Journal Paper

Abstract

Synthesis and characterization of silver/montmorillonite/chitosan bionanocomposites by chemical reduction method and their antibacterial activity

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2011 , Pages: 271-284, ISSN: Journal Paper

Abstract

Application of the ANN and RSM models for predicting the enzymatic synthesis of betulinic acid ester: A comparative study

Mansour Ghaffari Moghaddam,Faujan Bin H Ahmad,Mahiran Basri
ثبت نشده , ثبت نشده , Year : 2013 , Pages: 301-305, ISSN: Journal Paper

Abstract

Comparison of response surface methodology and artificial neural network in predicting the microwave-assisted extraction procedure to determine zinc in fish muscles.

Mansour Ghaffari Moghaddam,Mostafa Khajeh
ثبت نشده , Food and Nutritio Science , Year : 2011 , Pages: 803-808, ISSN:2157-944X Journal Paper

Abstract

Various Botanical Sources of Betulinic acid: A Review

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2012 , Pages: 4843-4846, ISSN: Journal Paper

Abstract

Biological Activity of Betulinic acid: A Review

Mansour Ghaffari Moghaddam,Alireza Samzadeh-Kermani
ثبت نشده , ثبت نشده , Year : 2012 , Pages: 119-123, ISSN: Journal Paper

Abstract

Optimization of Microwave Extraction for Determination of Iron and Manganese in Cereal Flour Using FAAS: Doehlert Design

Mansour Ghaffari Moghaddam,Mostafa Khajeh
Russia , Russian Agricultural Sciences , Year : 2012 , Pages: 275-280, ISSN:1068-3674 Journal Paper

Abstract

Response surface modeling of betulinic acid pre-concentration from medicinal plant samples by miniaturized homogenous liquid-liquid extraction and its determination by high performance liquid chromatography

Mansour Ghaffari Moghaddam,Mostafa Khajeh,,بهروز خواجه
ثبت نشده , ثبت نشده , Year : ثبت نشده , Pages: -, ISSN: Journal Paper

Abstract

بررسي كشت مخلوط ذرت (Zea mays L.) و كدو (Cucurbita sp. )و اثر آن بر كنترل علفهاي هرز

منصور غفاری مقدم,سید احمد قنبری,قديري حسين ,محمود صفري
ايران ، علوم گیاهان زراعی ایران ، سال : 2010 ، صفحات : 43-55، شاپا: 2008-4811 مقاله در مجله

چکیده

Artificial neural network modeling of p-cresol photodegradation

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2013 , Pages: 1-7, ISSN: Journal Paper

Abstract

Plant mediated green synthesis and antibacterial activity of silver nanoparticles using Crataegus douglasii fruit extract

Mansour Ghaffari Moghaddam,
ثبت نشده , ثبت نشده , Year : 2014 , Pages: 739-744, ISSN: Journal Paper

Abstract

Green synthesis of silver nanoparticles using plant extracts

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2014 , Pages: 548-557, ISSN: Journal Paper

Abstract

Wavelet neural network based on genetic algorithm for modeling enzymatic esterification of betulinic acid using phthalic anhydride as acylating agent

Mansour Ghaffari Moghaddam
India , BioTechnology: An Indian Journal , Year : 2014 , Pages: 467-474, ISSN:0974-7435 Journal Paper

Abstract

Application of response surface methodology in enzymatic synthesis: A review

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2014 , Pages: 252-262, ISSN: Journal Paper

Abstract

Application of Artificial Neural Network for Multivariate Optimization in the Lipase-Catalyzed Esterification Reaction of BetulinicAcid with Phthalic Anhydride

Mansour Ghaffari Moghaddam
India , International Journal of ChemTech Research , Year : 2014 , Pages: 2469-3474, ISSN:0974-4290 Journal Paper

Abstract

Synthesis, characterization and antibacterial properties of a novel nanocomposite based on polyaniline/polyvinyl alcohol/Ag

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2014 , Pages: 846-855, ISSN: Journal Paper

Abstract

Industrial applications of enzymes

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2014 , Pages: 341-361, ISSN: Journal Paper

Abstract

Application of a hybrid artificial neural network–genetic algorithm approach to optimize the lead ions removal from aqueous solutions using intercalated tartrate-Mg–Al layered double hydroxides

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2014 , Pages: 2-7, ISSN: Journal Paper

Abstract

A rapid synthesis of silver nanoparticles using a radical initiator under UV light and evaluation of their antibacterial activities

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2014 , Pages: 2257-2261, ISSN: Journal Paper

Abstract

Characterization and antibacterial activity of plant mediated silver nanoparticles biosynthesized using Scrophularia striata flower extract

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2015 , Pages: 538-546, ISSN: Journal Paper

Abstract

Enzymatic processes in alternative reaction media: a mini review

Mansour Ghaffari Moghaddam
ثبت نشده , ثبت نشده , Year : 2015 , Pages: 1-7, ISSN: Journal Paper

Abstract

Iron species supported on a mesoporous zirconium metal-organic framework for visible light driven synthesis of quinazolin-4(3H)-ones through one-pot three-step tandem reaction

َAli Reza Oveisi,,Mansour Ghaffari Moghaddam,Mostafa Khajeh,
USA , Journal of Colloid and Interface Science , Year : 2019 , Pages: 214-226, ISSN:0021-9797 Journal Paper

Abstract

A bioinspired iron(III)porphyrinic Zr-MOF, PCN-222(Fe), was modified by post-synthetic cluster metalation with iron(III) chloride, as a cheap, earth-abundant, and environmentally friendly metal precursor, towards formation a new multifunctional MOF, namely Fe@PCN-222(Fe). The MOF consists of bimetallic (Zr-oxo-Fe) nodes linked by Fe(III)porphyrin struts. The cluster metalation and pre-activation treatment of PCN-222(Fe) were performed cooperatively using the FeCl3. The respective MOF was characterized through various techniques, such as FT-IR, PXRD, ICP-AES, BET surface area, SEM, UV–Vis DRS, TGA/ DSC, PL, and XPS analyses. The solid showed catalytic activity for one-pot tandem synthesis of quinazolin-4(3H)-ones from alcohols and 2-aminobenzamide through a three-consecutive-step reaction (oxidation-cyclization-oxidation) under visible light irradiation using air or oxygen without adding any additive. In addition, its catalytic performance was superior to that of the bare PCN-222(Fe) and the corresponding homogeneous catalysts. The experiments indicate that the solid MOF acts as both a photoredox and Lewis acid catalyst. Hot-filtration and Fe-leaching tests as well as reusability experiments confirm that the nominal MOF acts as an efficient reusable heterogeneous catalyst for at least three runs without significant decrease in its activity. This work demonstrates the potential of using MOFs as supports for single-site metal species towards preparation of multifunctional MOFs for modern organic transformations combining photocatalysis and catalysis.

A hybrid material composed of an amino-functionalized zirconium-based metal-organic framework and a urea-based porous organic polymer as an efficient sorbent for extraction of uranium(VI)

َAli Reza Oveisi,,Mostafa Khajeh,Mansour Ghaffari Moghaddam,Saba Daliran
Austria , Microchimica Acta , Year : 2018 , Pages: 469-477, ISSN:0026-3672 Journal Paper

Abstract

An amino-functionalized zirconium metal-organic framework was composed with a 3D urea-based porous organic polymer to give a hybrid material termed UiO-66-NH2/urea-POP. The material was characterized by Fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, and Brunauer-Emmett-Teller surface area measurements. It is shown to be a viable sorbent for solid-phase extraction of uranium from water samples. Parameters such as the pH value of the sample, amount of adsorbent, type and volume of eluent, adsorption and desorption time, and sample volume were optimized. Uranyl ion was quantified by using UV-vis spectrophotometry by using 1-(2- pyridyl-azo)-2-naphthol as the indicator. Figures of merits include (a) a maximum sorption capacity of 278 mg g−1; (b) a detection limit of 0.6 μg L−1; and (c) intra-day and inter-day precisions (for n = 5 at a concentration of 100 μg L−1) of 4.8 and 1.9%, respectively. The sorbent can be recycled, and no significant change was observed in the capacity and repeatability of the sorbent after seven extractions. The high surface area, metal-binding sites, and stability of the sorbent makes it a most viable tool for efficient and fast extraction and removal of uranium.

Insecticidal effects of zinc oxide nanoparticles and Beauveria bassiana TS11 on Trialeurodes vaporariorum (Westwood, 1856) (Hemiptera: Aleyrodidae)

نجمه (Najmeh) صاحب زاده (Sahebzadeh),,Mansour Ghaffari Moghaddam,Ali Mirshekar
Slovenia , Acta Agriculturae Slovenica , Year : 2016 , Pages: 299-309, ISSN:1581-9175 Journal Paper

Abstract

Greenhouse whitefly, Trialeurodes vaporariorum is a major pest of horticultural and ornamental plants and is usually controlled with insecticides or biological control agents. In the current study, we examined the effects of synthesized zinc oxide nanoparticles (ZnO NPs) and Beauveria bassiana TS11 on T. vaporariorum adults. ZnO NPs were synthesized by precipitation method. Field emission scanning electron microscope images indicated that ZnO NPs were noncompacted uniformly. X-ray diffraction results confirmed the hexagonal wurtzite structure of ZnO NPs. Fourier transform infrared analysis showed an intense absorption peak at a range of 434-555 cm-1 related to Zn-O bond. In bioassays, adults were exposed to different concentrations of ZnO NPs (3, 5, 10, 15, 20 mg l-1) and fungi (104, 105, 106, 107, 108 spores ml-1). LC50 values for ZnO NPs and fungi were 7.35 mg l-1and 3.28×105 spores ml-1, respectively. Mortality rates obtained with ZnO NPs and fungi at the highest concentration were 91.6 % and 88.8 %, respectively. The results indicate a positive effect of ZnO NPs and B. bassiana TS11on adults. The current study was conducted under laboratory conditions, therefore, more studies are needed in field.

Toxicity of N-alkyl Derivatives of Chitosan Obtained from Adult of Chrotogonus trachypterus (Orthoptera, Acrididae) against the Wheat, Cabbage and Oleander Aphid (Hemiptera: Aphididae) Species

نجمه (Najmeh) صاحب زاده (Sahebzadeh),سیدکاظم صباغ,Mansour Ghaffari Moghaddam
Jordan , Jordan Journal of Biological Science , Year : 2017 , Pages: 49-55, ISSN:1995-6637 Journal Paper

Abstract

Chitosan and its derivatives have received attention as alternatives to pesticides in agriculture. Insects are a good source for chitosan isolation. In the present study, chitosan was obtained from Chrotogonus trachypterus (Orthoptera, Acrididae), and its N-alkyl derivatives were synthesized. Experiments were conducted to assay their aphicidal activity against three aphid species. All derivatives had a higher aphicidal action (> 98%) than pure chitosan (> 15.2%) against aphid species. N-(3-phenyl butyl) chitosan and N-(ethyl butyl) chitosan were the most and least active derivatives. Results confirmed that the chemical modification of chitosan increased the aphicidal activity. A comparison of the aphicidal activities confirmed that N-alkyl derivatives of commercial chitosan had more toxic effects on aphid species than derivatives of grasshopper chitosan. No significant differences were observed between the two groups of commercial and C. trachypterus chitosan derivatives. This encourages us to introduce N-alkyl derivatives of grasshopper chitosan as a promising alternative source of aphicides in future.

Determination of gold in water samples using electromembrane extraction

Mostafa Khajeh,Maryam Dahmardeh,,Ali Khatibi,Mansour Ghaffari Moghaddam
English , Journal of Dispersion Science and Technology , Year : 2018 , Pages: 311-315, ISSN:0193-2691 Journal Paper

Abstract

determination of gold from water samples prior to UV-Vis spectrophotometry. An artificial neural network (ANN) combined with imperialist competitive algorithm (ICA) has been applied to optimize the EME. The effective parameters including pH of acceptor phase, extraction time (t), volume of sample solution (V), stirring rate (S), and voltage (E) were chosen as input variables and the extraction recovery of gold was considered as output variable. The mean of squared error (i.e., 0.0009) and determination coefficient (i.e., 0.9821) were applied to estimate the performance of the ANN model. The limit of detection was 4.5 μg L

New porphyrins: synthesis, characterization, and computational studies

َAli Reza Oveisi,pooya karimi,Hojat Samareh Delarami,صبا دلیران,احمد خرم آبادی زاد,Mostafa Khajeh,esmael sanchooli,Mansour Ghaffari Moghaddam
Netherlands , Molecular Diversity , Year : 2019 , Pages: 1-10, ISSN:1381-1991 Journal Paper

Abstract

New trans-A2B2-porphyrins substituted at phenyl positions were synthesized from 4-methylphthalic acid as a starting material through sequential multistep reactions. These macrocycles were characterized by 1H NMR, 13C NMR, 19F NMR, 1H–1H COSY NMR, and MALDI-TOF mass spectrometry. Computational studies were performed on the porphyrins to investigate various factors such as structural features, electronic energy, energy gaps, and aromaticity. Energy band gap values of these compounds especially N-hydroxyphthalimide-functionalized porphyrins were small that makes them as good candidates for solar cell systems and photocatalysis. Relationships between electronic energies and aromaticity of the compounds were then investigated. The data indicated that the aromaticity features at the center of two series of these compounds (fluorinated and non-fluorinated porphyrins) were in the opposite manner.

Determination of Amadori Product in Glycated Human Serum Albumin by Spectroscopy Methods

,Mansour Ghaffari Moghaddam,Mostafa Khajeh,Nader Sheibani
Germany , ChemistrySelect , Year : 2018 , Pages: 7018-7022, ISSN:2365-6549 Journal Paper

Abstract

The Amadori product is a stable intermediate in the glycation process, and its increased formation is a marker of hyperglycemia in diabetes mellitus. Its accumulation in the body contributes to pathological complications of diabetes including diabetic nephropathy and retinopathy, and cardiovascular diseases. In this study the effect of 3-b-hydroxybutyrate on the production of Amadori products and structural changes of human serum albumin (HSA) after incubation with glucose was investigated using FT-IR, circular dichroism (CD), and UV-visible and fluorescence spectroscopy. Our results showed that the production of Amadori products in HSA incubated with glucose was decreased in the presence of 3-b-hydroxybutyrate. The glycation-mediated alterations in HSA secondary and tertiary structures were also reduced in the presence of 3-b-hydroxybutyrate. These changes were attributed to reduced formation of glucose covalent bonds with the HSA lysine residues in the presence of 3-b-hydroxybutyrate. Thus, 3-b-hydroxybutyrate reduced the production of Amadori products by reacting with lysine residues and decreasing HSA covalent modifications by glucose.

Contributions of metalloporphyrin linkers and Zr6 nodes in gas adsorption on a series of bioinspired zirconium-based metal-organic frameworks: A computational study

َAli Reza Oveisi,Hojat Samareh Delarami,Mostafa Khajeh,Sedigheh Mirjahanshahi,Abdolhossein Haghani,Saba Daliran,Mansour Ghaffari Moghaddam
Netherlands , Journal of Molecular Structure , Year : 2020 , Pages: 0-0, ISSN:0022-2860 Journal Paper

Abstract

In this study, gases adsorption on a series of mesoporous zirconium-based metal-organic framework analogues [PCN-222(M) where M = Mg, Fe, Co, Ni, Cu, and Zn)] has been evaluated by quantum mechanical calculations. These bioinspired frameworks are one of the most stable MOF materials, comprising the metalloporphyrin linkers/building blocks and the Zr6 nodes. The metalloporphyrins, open-zirconium coordination sites, and terminal hydroxyl groups on the nodes have been considered for the interactions. The structural and electronic properties of the complexes were investigated via the atoms in molecules (AIM), natural bond orbital (NBO), and harmonic oscillator model of aromaticity (HOMA) index. The results showed that the ironporphyrin is an appropriate candidate for the ammonia capture. It is observed that the hydrogen bond interactions of H2O with the hydroxyl groups of node are stronger than the others, while the interactions of NH3 with the open-zirconium coordination sites are stronger than the others. The all results indicated that the PCN-222(Fe) is selective for adsorption of NH3 over the other gases.

A Pyridyltriazol Functionalized Zirconium Metal–Organic Framework for Selective and Highly Efficient Adsorption of Palladium

َAli Reza Oveisi,Saba Daliran,Mahbobeh Ghazagh-Miri,Mostafa Khajeh,Sergio Navalón,Mercedes Âlvaro,Mansour Ghaffari Moghaddam,Hojat Samareh Delarami,Hermenegildo García
USA , ACS Applied Materials and Interfaces , Year : 2020 , Pages: 25221-25232, ISSN:1944-8244 Journal Paper

Abstract

This work reports the synthesis of pyridyltriazol-functionalized UiO-66 (UiO stands for University of Oslo), namely, UiO-66-Pyta, from UiO-66-NH2 through three postsynthetic modification (PSM) steps. The good performance of the material derives from the observation that partial formylation (∼21% of −NHCHO groups) of H2BDC-NH2 by DMF, as persistent impurity, takes place during the synthesis of the UiO- 66-NH2. Thus, to enhance material performance, first, the as-synthesized UiO-66-NH2 was deformylated to give pure UiO-66-NH2. Subsequently, the pure UiO-66-NH2 was converted to UiO-66-N3 with a nearly complete conversion (∼95%). Finally, the azide−alkyne[3+2]-cycloaddition reaction of 2-ethynylpyridine with the UiO-66-N3 gave the UiO-66-Pyta. The porous MOF was then applied for the solid-phase extraction of palladium ions from an aqueous medium. Affecting parameters on extraction efficiency of Pd(II) ions were also investigated and optimized. Interestingly, UiO-66-Pyta exhibited selective and superior adsorption capacity for Pd(II) with a maximum sorption capacity of 294.1 mg g−1 at acidic pH (4.5). The limit of detection (LOD) was found to be 1.9 μg L−1. The estimated intra- and interday precisions are 3.6 and 1.7%, respectively. Moreover, the adsorbent was regenerated and reused for five cycles without any significant change in the capacity and repeatability. The adsorption mechanism was described based on various techniques such as FT-IR, PXRD, SEM/EDS, ICPAES, and XPS analyses as well as density functional theory (DFT) calculations. Notably, as a case study, the obtained UiO-66-Pyta after palladium adsorption, UiO-66-Pyta-Pd, was used as an efficient catalyst for the Suzuki−Miyaura cross-coupling reaction.

A porous multifunctional and magnetic layered graphene oxide/3D mesoporous MOF nanocomposite for rapid adsorption of uranium(VI) from aqueous solutions

َAli Reza Oveisi,,Mostafa Khajeh,Saba Daliran,Mansour Ghaffari Moghaddam,Hojat Samareh Delarami
south korea , Journal of Industrial and Engineering Chemistry , Year : 2021 , Pages: 322-332, ISSN:1226-086X Journal Paper

Abstract

A novel adsorbent, GO/Fe3O4/OPO3H2/PCN-222, was successfully synthesized via graphene oxide (GO) modification with magnetic particles, phosphorous-containing groups, and a mesoporous Zr-MOF, PCN- 222 (PCN stands for Porous Coordination Network), respectively, to give the nominal composite. The last step was through a solvent-assisted ligand incorporation technique. Morphological, structural, and physicochemical properties of the hybrid material was assessed by FT-IR, PXRD, SEM/EDX, BET surface area, VSM, TGA/DSC, UV–vis DRS, and ICP-OES analyses. This solid was then used for dispersive solid phase extraction of uranium ions dissolved in water. Several parameters including pH of solution, extraction and desorption times, amount of adsorbent, and type and concentration of elution solvent were investigated and optimized. The maximum adsorption capacity of adsorbent was found to be 416.7 mg g1 (pH, 6.2; amount of adsorbent, 5.0 mg; extraction time, 3.0 min) beyond what was achievable with the individual components. In addition, various coordination modes between the multifunctional adsorbent and uranyl ions were investigated by DFT calculations in details, revealing some favorable non-covalent cation–p interaction and strong binding of free-base porphyrin, carboxyl and phosphorous-containing groups to the uranium ions. Under optimized conditions, high determination coefficient (R2 = 0.9994) was obtained and limit of detection and relative standard deviation were found 0.9 mg L-1 and 2.7%, respectively.

Iron nanoparticles: Synthesis and Interaction Studies with Calf Thymus DNA

,Mansour Ghaffari Moghaddam
بیست و ششمین سمینار شیمی آلی ایران , Year : 2019 Conferance Paper

Abstract

Inorganic nanoparticles and combination of inorganic nanoparticles with organic materials to form hybrids possess unique physical, chemical, optical and electrical properties which make them different and more applicable than large size materials. These types of platforms can be synthesized by different organic , inorganic or hybrid of organic and inorganic materials but among all these inorganic platformsare of most important for diagnosis and simultaneous therapy due to their easy modification, stability and high drug loading capacity [1]. Metal nanoparticles specifically gold nanoparticles have abundant use in the field of biotechnology and biomedicine because they have large surface bio conjugation with molecular probes[2]. In this study, we synthesized Au- Peptide nanoparticles using microwave, Sonochemistry and organic reducing agents and their anticancer effects were investigated. The resulting Au-nanoparticles were characterized using UV-Vis spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), particle size analyzer and fourier transform infrared spectroscopy (FT-IR) and transmission electron microscopy (TEM) techniques. The interaction of calf thymus DNA with Au-nanoparticles has been investigated following UV-Vis spectroscopic studies at 300 and 310 K. [L]1/2, ΔG0, ΔS0, ΔH0 values were obtained at 300 K, respectively, 0.24352 mM, 26.729 (KJ/mol), 0.8574 (KJ/mol.k), 286.435 (KJ/mol) and at 310 K, respectively, 0.33248 mM, 19.17 (KJ/mol), 0.8587 (KJ/mol), 286.435 (KJ/mol). Kapp, n and g values were obtaind 83.24, 6.74 and 4 at 310 K, respectively.

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